Nucleophilic Catalysis of Reactions of Tricarbonyl(trimethylsilylarene)chromium Complexes with Electrophiles
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چکیده
منابع مشابه
Nucleophilic Catalysis of Reactions of Tricarbonyl(trimethylsilylarene)chromium Complexes with Electrophiles
For the nitroand chlorophenyl(trimethyl)silanes, the relative reactivity correlates well with the al-substituent cons tan t~[~"] , but diverges significantly from the order of stabilization of the phenyl anions which would be essential intermediates for a nucleophilic d e ~ i l y l a t i o n l ~ ~ ~ . The ui correlation holds also for the other arylsilyl substrates (Ic)-(l j) in Table 1; the re...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition in English
سال: 1981
ISSN: 0570-0833,1521-3773
DOI: 10.1002/anie.198102661